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Rias is filled with a competitive spirit toward the three: Rias, who came early to tempt him, the kitten who is rapidly approaching, and Elsa, who is becoming increasingly proactive. In the midst of the intense rivalry, Ichiro is fully enjoying his blissful and indulgent life. On the other hand, while enjoying a peaceful daily routine, the members of the Supernatural Research Club are gradually preparing for the ranking game against the Bael family and the school trip for Ichiro and his friends. The destination for the school trip is Kyoto, a city with different mythological systems. Ichiro and his friends are looking forward to sightseeing, but as soon as they arrive, they are caught up in a conflict between the Chaos Faction and the demons residing in the ancient capital. Ichiro, in order to protect the Kyoto that Rias loves, begins to explore new "possibilities"...